منابع مشابه
Chelating bis-N-heterocyclic carbene complexes of iron(ii) containing bipyridyl ligands as catalyst precursors for oxidation of alcohols.
Chelating bis-N-heterocyclic carbene (bis-NHC) complexes of iron(ii) containing pyridyl ligands have been prepared by the reaction of [FeCl2L] [L = bipy (1), phen (2)] with [LiN(SiMe3)2] and a bis(imidazolium) salt. The [Fe(bis-NHC)L(I)2] complexes were active pre-catalysts in the oxidation of 1-phenylethanol with tert-butyl hydroperoxide in neat conditions, affording a quantitative yield of ac...
متن کاملDetermination of iron in solutions containing iron complexes.
A method of estimating the iron content of solutions containing haemoglobin, ferritin, or ferrioxamine is described. Iron is released by treatment with acid permanganate and ascorbic acid before conventional determination by an Auto Analyzer technique.
متن کاملIron (II) and Iron(III) complexes of organophosphonic acids
Polynuclear Iron(II) and Iron(III) derivatives of 1-Aminoethylidenediphosphonic acid (AEDP, H4L 1), Alpha-Amino benzylidene diphosphonic acid (ABDP, H4L 2), 1-Amino-2-carboxyethane-1,1diphosphonic acid (ACEDP, H5L 3), 1,3 Diaminopropane-1,1,3,3-tetraphosphonic acid (DAPTP, H8L 4), Diethylene triamine –N,N,N’,N’,N’’N”-penta ( methylene phosphonic ) acid (DETAPMPO, H10L 5),and Diethylene triamine...
متن کاملsynthesis of binuclear platinum complexes containing biphosphine ligand
هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
Efficient dehydrogenation of formic acid using an iron catalyst.
Hydrogen is one of the essential reactants in the chemical industry, though its generation from renewable sources and storage in a safe and reversible manner remain challenging. Formic acid (HCO(2)H or FA) is a promising source and storage material in this respect. Here, we present a highly active iron catalyst system for the liberation of H(2) from FA. Applying 0.005 mole percent of Fe(BF(4))(...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 2017
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.20170071